Some hydrogen bonds between methanol molecules are disrupted after adding acetone to methanol.
Select the appropriate option:

1.  At specific compositions, a methanol-acetone mixture will form a minimum boiling azeotrope and show a positive deviation from Raoult’s law.
2. At specific compositions, a methanol-acetone mixture will form a maximum boiling azeotrope and show a positive deviation from Raoult’s law.
3. At specific compositions, a methanol-acetone mixture will form a minimum boiling azeotrope and show a negative deviation from Raoult’s law.
4. At specific compositions, a methanol-acetone mixture will form maximum boiling azeotrope and show a negative deviation from Raoult’s law.